(i) Introduction (ii) First law of Thermodynamics and its mathematical statement. (iii) Ideas about Heat, Work and Energy (iv) Second law of thermodynamics - Reversible and irreversible changes, isobaric, isochoric adiabatic processes; Entropy, Free Energy. Spontaneity of a chemical change. ?G° = -2.303 RT logKeq. (iv) Second law of thermodynamics - Reversible and irreversible changes, isobaric, isochoric adiabatic processes; Entropy, Free Energy. Spontaneity of a chemical change. ?G° = -2.303 RT logKeq. (iv) Second law of thermodynamics - Reversible and irreversible changes, isobaric, isochoric adiabatic processes; Entropy, Free Energy. Spontaneity of a chemical change. ?G° = -2.303 RT logKeq. (iv) Second law of thermodynamics - Reversible and irreversible changes, isobaric, isochoric adiabatic processes; Entropy, Free Energy. Spontaneity of a chemical change. ?G° = -2.303 RT logKeq. (iv) Second law of thermodynamics - Reversible and irreversible changes, isobaric, isochoric adiabatic processes; Entropy, Free Energy. Spontaneity of a chemical change. ?G° = -2.303 RT logKeq. (v) Third Law of Thermodynamics - statement only (vi) Thermochemistry:(a) Definitions (b) Constancy in the heat of neutralisation (c) Calorific value of a fuel (d) Hess’s law of constant heat summation - simple problems based on the above definitions and concepts
1. Some Basic Concepts of Chemistry 2. Atomic Structure 3. Periodic Table 4. Chemical Bonding 5. The Gaseous State 6. Surface Chemistry 7. Chemical Kinetics 8. Chemical Energetics 9. Study of Representative Elements: Group 1, 2, 13, 14, 15 10. Preparation, properties and uses of Compounds of Groups 1, 2, 13, 14, 15 11. Redox Reactions 12. Introduction to Organic Chemistry 13. Isomerism 14. Types of Chemical Reactions and their Mechanisms 15. Aliphatic and Aromatic Hydrocarbons 16. Applications of Chemicals 17. Environmental Chemistry