11.0. Introduction 11.1 Classification and Nomenclature 11.2 Nature of C-X Bond 11.3.Methods of Preparation : Alkyl Halides and Aryl Halides- from Alcohols, from Hydrocarbons (a) By Free Radical Halogenations – (b) By Electrophilic Substitution (c) By replacement of Diazonium Group (Sand-Meyer Reaction) (d) By the Addition of Hydrogen Halides and Halogens to Alkenes - By Halogen Exchange (Finkelstein reaction) 11.3.Methods of Preparation : Alkyl Halides and Aryl Halides- from Alcohols, from Hydrocarbons (a) By Free Radical Halogenations – (b) By Electrophilic Substitution (c) By replacement of Diazonium Group (Sand-Meyer Reaction) (d) By the Addition of Hydrogen Halides and Halogens to Alkenes - By Halogen Exchange (Finkelstein reaction) 11.3.Methods of Preparation : Alkyl Halides and Aryl Halides- from Alcohols, from Hydrocarbons (a) By Free Radical Halogenations – (b) By Electrophilic Substitution (c) By replacement of Diazonium Group (Sand-Meyer Reaction) (d) By the Addition of Hydrogen Halides and Halogens to Alkenes - By Halogen Exchange (Finkelstein reaction) 11.3.Methods of Preparation : Alkyl Halides and Aryl Halides- from Alcohols, from Hydrocarbons (a) By Free Radical Halogenations – (b) By Electrophilic Substitution (c) By replacement of Diazonium Group (Sand-Meyer Reaction) (d) By the Addition of Hydrogen Halides and Halogens to Alkenes - By Halogen Exchange (Finkelstein reaction) 11.3.Methods of Preparation : Alkyl Halides and Aryl Halides- from Alcohols, from Hydrocarbons (a) By Free Radical Halogenations – (b) By Electrophilic Substitution (c) By replacement of Diazonium Group (Sand-Meyer Reaction) (d) By the Addition of Hydrogen Halides and Halogens to Alkenes - By Halogen Exchange (Finkelstein reaction) 11.3.Methods of Preparation : Alkyl Halides and Aryl Halides- from Alcohols, from Hydrocarbons (a) By Free Radical Halogenations – (b) By Electrophilic Substitution (c) By replacement of Diazonium Group (Sand-Meyer Reaction) (d) By the Addition of Hydrogen Halides and Halogens to Alkenes - By Halogen Exchange (Finkelstein reaction) 11.3.Methods of Preparation : Alkyl Halides and Aryl Halides- from Alcohols, from Hydrocarbons (a) By Free Radical Halogenations – (b) By Electrophilic Substitution (c) By replacement of Diazonium Group (Sand-Meyer Reaction) (d) By the Addition of Hydrogen Halides and Halogens to Alkenes - By Halogen Exchange (Finkelstein reaction) 11.3.Methods of Preparation : Alkyl Halides and Aryl Halides- from Alcohols, from Hydrocarbons (a) By Free Radical Halogenations – (b) By Electrophilic Substitution (c) By replacement of Diazonium Group (Sand-Meyer Reaction) (d) By the Addition of Hydrogen Halides and Halogens to Alkenes - By Halogen Exchange (Finkelstein reaction) 11.4 Physical Properties- Melting and Boiling Points, Density and Solubility 11.4 Physical Properties- Melting and Boiling Points, Density and Solubility 11.5 Chemical Reactions : Reactions of Haloalkanes (I) Nucleophilic Substitution reactions (a) SN² Mechanism (b) SN¹ Mechanism © Stereochemical Aspects of Nucleophilic Substitution Reactions - Optical Activity (I) Nucleophilic Substitution reactions (a) SN² Mechanism (b) SN¹ Mechanism © Stereochemical Aspects of Nucleophilic Substitution Reactions - Optical Activity (I) Nucleophilic Substitution reactions (a) SN² Mechanism (b) SN¹ Mechanism © Stereochemical Aspects of Nucleophilic Substitution Reactions - Optical Activity (ii) Elimination Reactions (iii) Reaction with metals- Reactions of Haloarenes: (i) Nucleophilic substitution (ii) Electrophilic substitution and (iii) Reaction with metals (iii) Reaction with metals- Reactions of Haloarenes: (i) Nucleophilic substitution (ii) Electrophilic substitution and (iii) Reaction with metals (iii) Reaction with metals- Reactions of Haloarenes: (i) Nucleophilic substitution (ii) Electrophilic substitution and (iii) Reaction with metals (iii) Reaction with metals- Reactions of Haloarenes: (i) Nucleophilic substitution (ii) Electrophilic substitution and (iii) Reaction with metals 11.6 Polyhalogen Compounds: Uses and Environmental Effects of Dichloromethane, Richloromethane, Triiodomethane, Tetrachloro Methane, Freons and DDT 11.6 Polyhalogen Compounds: Uses and Environmental Effects of Dichloromethane, Richloromethane, Triiodomethane, Tetrachloro Methane, Freons and DDT 11.6 Polyhalogen Compounds: Uses and Environmental Effects of Dichloromethane, Richloromethane, Triiodomethane, Tetrachloro Methane, Freons and DDT
1 - Solid State 2 - Solutions 3 - Electrochemistry and Chemical Kinetics Electrochemistry 4 - Surface Chemistry 5 - General Principles of Metallurgy 6 - The p-Block Elements Group 15 7 - d and f-Block Elements and Coordination Compounds - d and f-Block Elements 8 - Polymers 9 - Biomolecules 10 - Chemistry in Every Day Life 11 - Haloalkanes and Haloarenes 12 - Organic Compounds Containing C, H and O 13. Organic Compounds Containing Nirogen Amines